Safety Data Sheet
according to Federal Register
/ Vol. 77, No. 58 / March
26, 2021 / Rules and Regulations
Date of issue: 05/20/2015 Version: 1.0
SECTION
1: Identification of the substance/mixture and of the company/undertaking
|
Use of the substance/mixture
|
:
|
Cyanoacrylate Adhesive
|
RhinoTech Supplies, Inc.
2955
Lone Oak Circle, #2
Eagan,
MN 55121 United States
T 651-686-5027;
F 651-686-9745
info@rhinotechinc.com
|
Emergency
number
|
:
|
ChemTel, Inc. 800-255-3924, International 813-248-0585
|
SECTION 2: Hazards identification
GHS-US classification
|
Flam. Liq.
4
|
H227
|
|
Skin Irrit. 2
|
H315
|
|
Eye Irrit. 2A
|
H319
|
|
STOT SE 3
|
H335
|
GHS-US labelling
|
Hazard pictograms (GHS-US)
|
:
|
GHS07
|
|
Signal word
(GHS-US)
|
:
|
Warning
|
|
Hazard statements (GHS-US)
|
:
|
H227
- Combustible liquid H315 - Causes
skin irritation
H319 - Causes serious
eye irritation H335 - May cause
respiratory irritation
|
|
Precautionary statements (GHS-US)
|
:
|
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P271 -
Use only in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338
- If in eyes: Rinse
cautiously with water
for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing
P337+P313 - If eye
irritation persists: Get medical advice/attention
P501 - Dispose of contents/container to local, regional,
national, and international regulations.
|
Precautionary phrases Cyanoacrylate. Danger.
Bonds skin and eyes
in seconds. Contact through clothing
(cotton) may cause burns. Keep
out of the reach of children.
This product is not identified as a PBT
substance.
WARNING:
Cyanoacrylate. Eye irritant. Bonds skin and eyes in seconds. This adhesive
gives a virtually immediate, strong bond: apply only to surfaces to be bonded. Do not get adhesive
on your skin or other parts of your body,
or that of others. In case of body contact, flush with water. Seek
medical attention for any eye or internal contact. Keep out of the reach of children.
SECTION
3: Composition/information on ingredients
Full text of H-phrases: see section 16
Hazardous ingredients:
EN (English) Page 1
|
Name
|
Product identifier
|
%
|
GHS-US classification
|
|
ethyl-2-cyanoacrylate
|
(CAS No) 7085-85-0
|
>80%
|
Flam. Liq. 4, H227 Skin Irrit. 2, H315 Eye
Irrit. 2A, H319 STOT SE 3, H335
|
SECTION
4: First aid measures
|
First-aid measures general
|
:
|
If you feel unwell,
seek medical advice (show the label where possible). Never give anything by mouth to an unconscious person.
|
|
First-aid measures after inhalation
|
:
|
Overexposure may be irritating to the respiratory system. If breathing is difficult, remove
victim to fresh air and keep at rest
in a position comfortable for breathing. If you feel
unwell, seek medical advice.
|
|
First-aid measures after skin contact
|
:
|
Do not pull
bonded skin apart.
Gently wash with plenty of soap and water.
If skin irritation or rash occurs: Get
medical advice/attention. Contact through clothing can cause immediate polymerization, exothermic
reaction and burning. Removal of clothing
can remove bonded skin. Submerge
with water and soak affected area. Wear a plastic (not cotton) apron for added protection. Get immediate medical
advice/attention. If the lips are accidentally bonded, apply warm soapy water,
encourage maximum wetting
and pressure from
saliva inside the
mouth and peel or roll lips
apart. DO NOT TRY TO PULL LIPS APART. Burn: should be treated normally after the lump of cyanoacrylate is released from the tissue.
|
|
First-aid measures after eye contact
|
:
|
Immediately flush with
warm water for at least 15 minutes, get prompt medical attention and apply gauze patch. Cyanoacrylate will bond to eye protein and cause a lachrymatory effect which will help de-bond the
adhesive. Keep eye covered until de-bonding is complete (usually with 1-4
days). Get immediate medical attention.
|
|
First-aid measures after ingestion
|
:
|
This route
is not likely. Material will rapidly
polymerise in the mouth prior to ingestion. Ensure breathing
passages are not obstructed. Get immediate medical attention.
|
|
Symptoms/injuries
|
:
|
Irritation of the eye tissue. Causes skin and eye
irritation. Not expected to present a significant
hazard under anticipated conditions of normal use.
|
|
Symptoms/injuries after inhalation
|
:
|
May cause drowsiness or dizziness. May cause
respiratory irritation.
|
|
Symptoms/injuries after skin contact
|
:
|
May cause irritation
to skin. Cyanoacrylate bonds skin and eyes in seconds. In the case of large
spills on the skin, superficial burns may
occur.
|
|
Symptoms/injuries after eye contact
|
:
|
Causes eye irritation. Cyanoacrylate bonds
skin and eyes in seconds.
|
|
Symptoms/injuries after ingestion
|
:
|
Ingestion
unlikely. Material will rapidly polymerise in the
mouth prior to ingestion.
|
If exposed or concerned, get medical
advice and attention.
SECTION
5: Firefighting measures
|
Suitable extinguishing media
|
:
|
Alcohol-resistant foam. Dry powder. Carbon
dioxide. Water spray or fog.
|
|
Unsuitable extinguishing media
|
:
|
Solid water jet ineffective as extinguishing medium. Do not use a heavy water stream.
|
|
Fire hazard
|
:
|
Combustible
liquid.
|
|
Explosion hazard
|
:
|
In combustion emits toxic fumes of carbon dioxide, carbon monoxide and
nitrogen oxides.
|
|
Reactivity
|
:
|
No dangerous reactions
known under normal conditions of use.
|
|
Firefighting
instructions
|
:
|
Exercise caution
when fighting any chemical fire.
Use a water
spray to cool
exposed surfaces and to
protect fire-fighters. In case of major
fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Avoid (reject)
fire-fighting water to enter environment.
|
|
Protection during firefighting
|
:
|
Do not enter
fire area without
proper protective equipment, including respiratory protection.
|
|
Other information
|
:
|
Do not allow run-off from
fire fighting to enter drains or water courses.
|
SECTION 6: Accidental release measures
|
General measures
|
:
|
Eliminate every
possible source of ignition. Ensure
adequate ventilation. Avoid all contact with
skin, eyes, or clothing. Handle in accordance with good industrial hygiene and safety
practice.
|
|
6.1.1. For non-emergency pers
Protective
equipment
|
onnel
:
|
Use appropriate personal protection equipment (PPE).
|
|
Emergency procedures
|
:
|
Evacuate unnecessary personnel.
|
6.1.2. For
emergency responders
|
Protective
equipment
|
:
|
Equip cleanup crew with proper protection.
|
|
Emergency procedures
|
:
|
Evacuate unnecessary personnel. Keep away
from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. Use appropriate personal protection equipment (PPE).
Ventilate area.
|
Do not allow water (or moist air) contact with this material.
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers
or public waters.
|
For containment
|
:
|
Absorb excess
liquid spillage on inorganic adsorbent material such as fine sand,
brick dust etc. Place spent adsorbent in sealed packages and contact specialist waste disposal contractor.
Collect spillage.
|
|
Methods for cleaning up
|
:
|
Clear
up spills immediately and dispose of waste
safely. Take up liquid spill into absorbent
material, e.g.: sand, earth, vermiculite. Notify experts. Collect spillage.
Or flood with water slowly to
complete polymerization (~10:1, adhesive : water). Scrape off floor. Cured
material can be disposed of as non-hazardous waste.
|
See Heading 8. Exposure controls
and personal protection.
SECTION
7: Handling and storage
|
Precautions for safe handling
|
:
|
Avoid
contact of substance with water. Do no eat, drink or smoke when using this product. Do not get
in eyes, on skin, or on
clothing. Do not handle
until all safety
precautions have been read
and understood. Observe very strict hygiene - avoid contact. Keep away from
ignition sources.. Use only in a
well-ventilated area. Use personal protective equipment as required. Wash hands and other exposed
areas with mild soap
and water before
eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapour.
|
|
Hygiene measures
|
:
|
Do not eat, drink or smoke in areas where product is used. Handle in accordance
with good industrial hygiene
and safety practice. Wash hands and other
exposed areas with mild
soap and water before
eating, drinking or smoking and
when leaving work.
|
|
Technical measures
|
:
|
Comply with applicable regulations.
|
|
Storage conditions
|
:
|
Keep away
from direct sunlight. Keep container tightly
closed. Keep cool.
Keep in fireproof place. Store in a dry place. Keep container closed when not
in use.
|
|
Incompatible
products
|
:
|
Amines. Oxidizing agents.
Alkali metals. Water.
Alcohols. Strong bases.
Strong acids.
|
|
Incompatible
products
|
:
|
Sources of
ignition. Direct sunlight.
|
|
Storage temperature
|
:
|
Refrigerated
storage (2°C to 8°C) is recommended for optimum shelf
life.
|
SECTION 8: Exposure controls/personal protection
|
8.1. Control parameters
|
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
|
USA ACGIH
|
ACGIH TWA (ppm)
|
0.2 ppm
|
|
USA ACGIH
|
ACGIH STEL
(ppm)
|
0.2 ppm
|
|
Appropriate engineering controls
|
:
|
Ensure all national/local regulations are observed. Avoid all unnecessary exposure.
|
|
Personal protective equipment
|
:
|
Protective clothing. Protective goggles. Gloves. Full protective flameproof clothing. Respiratory
protection of the dependent type.
Avoid all unnecessary exposure.
|
|
Materials for protective clothing
|
:
|
Keep suitable chemically resistant protective
clothing readily available for emergency
use.
|
|
Hand protection
|
:
|
Wear chemically resistant protective gloves.
|
|
Eye protection
|
:
|
Chemical goggles or safety glasses.
|
|
Skin and body protection
|
:
|
Wear suitable protective clothing.
|
|
Respiratory
protection
|
:
|
Where exposure through inhalation may occur from
use, respiratory protection equipment is recommended.
Wear appropriate mask.
|
|
Other information
|
:
|
Do not eat, drink or smoke during use.
|
SECTION 9: Physical and chemical properties
|
Physical state
|
: Liquid
|
|
Appearance
|
: Colorless
liquid.
|
|
Colour
|
: Colorless.
|
|
Odour
|
: Irritating. sharp.
|
|
Boiling point
|
: > 212
°F
|
|
Flash point
|
: > 176
°F
|
|
Self ignition temperature
|
: > 450
°C
|
|
Vapour pressure
|
: < 0.2 mmHg @75°F
|
|
Specific gravity
|
: 1.06
|
|
Solubility
|
: Reacts with water. Soluble in Acetone.
|
|
Evaporation rate Hazardous Air Pollutants Percent volatile
Volatile Organic Compounds (VOC)
|
: Negligible
: <=0.1 % weight
[Test Method: Calculated]
: 90 - 95 % weight [Test Method: Estimated]
: 943 g/l [Test
Method: tested per EPA method 24]
|
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reactions known under normal conditions of use.
10.2. Chemical stability
Stable under normal conditions. Polymerises rapidly with water.
10.3. Possibility of hazardous reactions
Hazardous reactions will not occur under normal conditions. Polymerization may occur on exposure
to conditions or materials
listed below. Polymerization can be rapid.
10.4. Conditions to avoid
Direct sunlight. Heat, high temperature.
Moisture, humidity.
10.5. Incompatible materials
Amines. Water. Alkalis.
Oxidizing agent. Alcohols.
10.6. Hazardous decomposition products
Toxic fume.
Carbon monoxide. Carbon dioxide. Nitrogen oxides.
SECTION
11: Toxicological information
11.1. Information on
toxicological effects
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
LD50 oral rat
|
> 5000 mg/kg
bodyweight (Rat; Experimental value,Rat; Experimental value)
|
|
LD50 dermal
rabbit
|
> 2000 mg/kg
bodyweight (Rabbit; Experimental value,Rabbit; Experimental value)
|
SECTION 12: Ecological information
12.1. Toxicity
|
Ecology - general
|
:
|
Negligible
ecotoxicity.
|
12.2. Persistence and degradability
|
Chemence EC300
|
|
Persistence and degradability
|
No data available.
|
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
Persistence and degradability
|
No data available.
|
12.3. Bioaccumulative potential
|
Chemence EC300
|
|
Bioaccumulative potential
|
No bioaccumulative potential
|
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
Bioaccumulative potential
|
No bioaccumulative potential
|
12.4. Mobility in soil
Considered very low due to
rapid polymerization with water.
|
12.5. Other adverse effects
Other information
|
:
|
Avoid release to the environment.
|
SECTION 13: Disposal considerations
13.1. Waste treatment methods
|
Waste treatment methods
|
:
|
Remove waste in accordance with
local and/or national regulations.
|
|
Sewage disposal recommendations
|
:
|
Do not discharge into
drains or the environment.
|
|
Waste disposal recommendations
|
:
|
Transfer
to a suitable container and arrange for collection by specialized disposal company. Or polymerize
adhesive slowly with water (~10:1, adhesive : water). Hardened product can be disposed of as non-hazardous waste by licensed contractors. Dispose in a
safe manner in accordance with
local/national regulations.
|
|
Ecology - waste materials
|
:
|
Avoid release to the environment.
|
SECTION 14: Transport information
In accordance with DOT
|
Transport document description
|
:
|
NA1993 Combustible liquid, n.o.s., 9, III
|
|
UN-No.(DOT)
|
:
|
UN3334
|
|
DOT NA no.
|
:
|
NA1993
|
|
DOT Proper Shipping Name
|
:
|
Combustible liquid, n.o.s.
|
|
Department of Transportation (DOT) Hazard Classes
|
:
|
9 - Class 9 - Miscellaneous hazardous
material 49 CFR 173.140
|
|
DOT Symbols
|
:
|
D - Proper shipping name for domestic use
only, or to and from
Canada,G - Identifies PSN requiring a technical name
|
|
Packing group (DOT)
|
:
|
III - Minor
Danger
|
|
DOT Special Provisions (49 CFR 172.102)
|
:
|
IB3 - Authorized IBCs:
Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2,
31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor
pressure less than or equal
to 110 kPa at 50 C (1.1 bar at 122 F),
or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special
Provision IP8 in Table 2 for UN2672).
T1 - 1.5 178.274(d)(2)
Normal............. 178.275(d)(2)
T4 - 2.65
178.274(d)(2) Normal............. 178.275(d)(3)
TP1 -
The maximum degree of filling must
not exceed the degree of filling
determined by the following: Degree
of filling = 97 / (1 + a (tr - tf))
Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
|
|
DOT Packaging Exceptions (49 CFR 173.xxx)
|
:
|
150
|
|
DOT Packaging Non Bulk (49 CFR 173.xxx)
|
:
|
203
|
|
DOT Packaging Bulk (49 CFR 173.xxx)
|
:
|
241
|
|
DOT Quantity
Limitations Passenger aircraft/rail
(49 CFR 173.27)
|
:
|
60 L
|
|
DOT Quantity
Limitations Cargo aircraft only (49
CFR 175.75)
|
:
|
220 L
|
|
DOT Vessel Stowage Location
|
:
|
A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo
vessel and on a
passenger vessel.
|
|
Marine pollutant
|
:
|
No
|
Additional information
|
Environmentally hazardous
|
:
|
No
|
ADR
|
Transport document description
|
:
|
UN UN3334 aviation regulated liquid, n.o.s., 9
|
|
Class (ADR)
|
:
|
9 - Miscellaneous dangerous substances and articles
|
Transport by sea
|
Proper Shipping Name (IMDG)
|
:
|
Not regulated
|
Air transport
|
UN-No.(IATA)
|
:
|
UN3334
|
|
Proper Shipping Name (IATA)
|
:
|
aviation regulated liquid, n.o.s.
|
|
Class (IATA)
|
:
|
9 - Miscellaneous Dangerous Goods
|
|
Packing group (IATA)
|
:
|
III - Minor
Danger
|
SECTION 15: Regulatory information
15.1. US Federal regulations
|
EC700
|
|
SARA Section 311/312 Hazard Classes
|
Immediate (acute)
health hazard Delayed (chronic)
health hazard
|
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
Listed on the United States
TSCA (Toxic Substances Control Act) inventory
|
15.2. International regulations CANADA
EU-Regulations
EUH202:
Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children
Classification
according to Regulation (EC) No. 1272/2008 [CLP]
|
Skin Irrit.
2
|
H315
|
|
Eye Irrit. 2A
|
H319
|
|
STOT SE 3
|
H335
|
15.2.2. National regulations
No additional
information available
15.3. US State regulations Proposition 65 No Significant Risk Levels (NSRLs): This product
contains no ingredient under Proposition 65 that is classified as a significant risk.
|
ethyl-2-cyanoacrylate (7085-85-0)
|
|
U.S. - New Jersey - Right to Know Hazardous
Substance List
|
SECTION
16: Other information
Data sources :
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixturejs, amending and repealing
Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Full text of H-phrases:
|
Eye Irrit. 2A
|
Serious eye damage/eye
irritation, Category 2A
|
|
Flam. Liq. 4
|
Flammable liquids,
Category 4
|
|
Skin Irrit. 2
|
Skin
corrosion/irritation, Category 2
|
|
STOT SE 3
|
Specific target organ
toxicity — Single exposure, Category 3,
Respiratory tract irritation
|
|
H227
|
Combustible liquid
|
|
H315
|
Causes skin
irritation
|
|
H319
|
Causes serious eye irritation
|
|
H335
|
May cause respiratory irritation
|
WARNING: Cyanoacrylate. Danger.
Bonds skin and eyes
in seconds. Contact through clothing
(cotton) may cause burns. Keep
out of the reach of children.
HMIS III Rating
Health :
2 Moderate Hazard - Temporary or
minor injury may occur
Flammability :
2 Moderate Hazard
Physical :
1 Slight Hazard
SDS US (GHS HazCom 2012)
This document
has been prepared
in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910 .1200.
Information presented herein
has been compiled from sources considered to be accurate
and reliable, but is
not guaranteed to be so. Nothing herein shall be
considered as recommending practices or products in violation
of any patent, law or regulation. It is the user's
responsibility to determine the suitability
of any material for a specific purpose and to adopt such safety precautions as may be necessary. WE MAKE NO WARRANTIES REGARDING
THE PRODUCTS AND DISCLAIM ALL EXPRESS OR IMPLIED WARRANTIES, INCLUDING ANY WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE.